Breakthrough In Organic Chemistry: Creating Atropo-enriched Biaryls — Key Highlights
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Apr 30, 2024 · here we review the state of the art in the asymmetric synthesis of atropisomers with the help of selected examples.
Focus will be placed on the strategies that have emerged.
The importance of biaryls in natural products, drugs, catalysis, and organic materials has led to the development of numerous strategies for their synthesis, especially in the case of atropo.
We report the preparation of axially stereoenriched biphenyls by the coupling of in situ generated aryllithiums and arynes using chiral oxazoline auxiliaries.
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